There are a few really sweet corporate gigs out there, but you usually have to know someone or be in the right place at the right time.

The fractionals are run like mini-airlines, but you have to kiss the customers @ss. People who are rich enough to be in a fractional, but not rich enough to own the whole bird tend to be @ssholes. People that are REALLY rich are often pretty cool and good to work for; my experience anyway. On the airline side, I give an obnoxious customer one chance to lighten up, then he's leaving in handcuffs.

With your background you should probably look at a major airline, unless you can find some dude who owns a G-V. Or a job flying for the fed on the GS side would be better than a fractional, probably. Customs is a lot of fun. Or whatever they're called now.