Its been said before, but...
If someone will be attending their first 121 ground school and they have no background in turbine engines or advanced aircraft systems, prep is certainly advisable, but IMO only in a general sense. Most of the "pure piston" guys I know who went into a 121 ground school who had difficulty experienced those problems with turbine engines, pressurization, complex electrical and hydraulic systems.
It might not be a good thing to study specific limitations and systems from anything other than materials directly from the company you will be working for. Some companies have slightly different limitations or procedures than those put out by the manufacturer, and if you spend time learning rote limitations it might bite you in the rear come testing & oral time.
Your mileage may vary!