I hate to be discouraging, but while I'm sure they would absolutely talk to you, they'd probably say something along the lines of "come back when you meet the minimums." I had 3 internal recommendations last year but I was like 10 hours shy on the instrument time and didn't get a call until I got it. I know guys who have interned for the chief pilot or already work for the company as a ramper who still had to meet the bare published minimums of 1000/100. In my experience they haven't been one to budge from those for anyone. However, YMMV and it can't hurt to try.