With respect to corporate aviation there is little to no reason to sweat PIC time if you are currently beginning your career. I spent nearly 2yrs in the right seat of a sim starting out. For free no less. All that to advance my knowledge of systems and CRM so that when I was capable, I could move on. Your greatest asset in any corporate department is a positive attitutde and level of flexibility for the principal. The rest will fall into place. Best of luck and let us know what you decide-