You have to be in the right place at the right time right?

All the experience does help though. Part 135 experience helps and its a great world to meet people.

Alot of corporate owners charter aircraft then buy thier own, and with charter/management companies you will fly the owners on part 91 corporate flights, who will sometimes expand and have thier own flight departments.

Plus who want the pay of a regional, except Cape Air of course.