Late summer likely. Currently, all our BE99 Captain positions are filled.
We have a lot of new applicants, but if you haven't applied yet, please do. That'll at least get your application in front of the recruiters. They go through applications they already have before posting the position externally.
And keep an eye out at www.ameriflight.com/careers for openings. Things change often as we grow and our pilots transition to larger aircraft.

As for PR, you'd have a good chance of getting it. We have a handful of BE99 routes there and lots of opportunity for movement. Don't worry, you'll agree upon your location before signing your offer letter - no surprise moves!