Can you get your high performance and complex endorsment in a twin and it work on a single?

I only have my ppl right now but am wondering about this. The twin at my school is a Beechcraft BE-76 Duchess and I am looking at getting my ME now and then do my instrument training in the twin. While it would be about $4000 more than a single I think in the long run getting all that ME time would be better. Is this a good plan?