There was a long article in Aviation Week & Space Tech. a couple weeks back. I can't remember all the specifics but the article did say that they were looking for guys in the 5000 + hour range and would be using two pilots. The owner said that although the operation would permit the use of one pilot the company "felt safer" using two. I would take this to mean that as soon as they can prove their operation to the insurance company and investors they will ditch the guy in the right seat in favor of one more revenue seat.
I believe the starting salary was more than 50K. If you are a subscriber I'm sure you could find the article on their website