Start here:
http://www.faa.gov/licenses_certific...ia/n135toc.pdf
If you have a lot of money, or know somebody that does, you can have many people set it up for you. It will be expensive and you won't learn a thing
.
Your company might be up and you won't have any idea what to do, except pay people to do your work
.
You are young, start up a basic certificate with 1 airplane and go from there.
Do as much of it as you can yourself, you can ask for help and guidance (PM me if/ when you are ready and have questions). But be involved in it.
MEL's can be found here:
opspecs.com
Training manuals you will get from a training center like FSI or CAE.
FAA guidance for you to use:
Flight Standards Information System (FSIMS)
It will be very time consuming, and after you get your first revenue trip going, you be very satisfied
.
Just remember, it won't happen overnight or overyear for that matter.