There are corporate positions out there, you just have to know that many of these positions are not advertised. It is "word of mouth, or who you know". Having thousands and thousands of hours does not always get you hired either. In the corp. world customer service is everything.
The pay is as varied as the airplanes used (from a C172 to a BBJ). Like the others have said, finish your training first, then worry about where to go.