Thank you everyone for your responses. I am in a situation where my affiliation with my 141 school bridges me in with with a regional airline and I do not have to interview nor have minimum flight times. I have been instructing for a few years and wouldn't mind continuing to do so, but this is a great opportunity and one where I wouldn't have to job search, ect.
However, because I was not expecting something like this to be an option I planned for other things. As of now, it looks like my class date will be late this month/early next month and the wedding would be late July. I had planned a honeymoon for the 12 days after this, or the first two-ish weeks in August.
I realize that it is a long-shot, but I don't really know how scheduling works or if letting someone know about this far in advance would be able to work around anything at all.
Again, there are other things i could choose to do right now im my life, im young. But Im not sure I can turn down an opportunity like this to jump into the right seat. Thanks for the comments