The Risk would be centering around me not having been flying as a full time pilot for a while. The FO position would get me back up to speed quickly, and allow me time to learn the SOP.

I couldn't imagine that Cape hires people into the Captain without previous 135 experience. Would you tell me, or do you know whether Cape hires people who only have CFI experience like myself?

The entire issue is whether a person with ATP mins, but only CFI time is really qualified for this.