I had posted earlier in this thread, but that was 30 or so pages ago.
I was at PS for over 5 years. Started with about 700 hours, left with about 3000. I have been gone about 3.5 years. I do not regret it in the least, despite being stuck as an F/O for 3 years. But the job market back then was 100% different than it is now.
Here is my advice. If you have less than 1500 hours, Planesense would be a good place to go to get some real world experience in a two person cockpit in all kinds of weather to all kinds of different airports. Once you hit 1500 hours, go work for a regional.
If you have 1500 hours or more, go to a regional. You'll make more money, get multi jet experience, and once you're off reserve, probably have a better QOL. You'll have many more career options once you've been there for a few years, be it major airlines or corporate/charter. The PC-12 is an awesome airplane, but it is still a single engined aircraft. I'm a captain on a Hawker, with about 4500 hours, but I can't apply at UPS cause I don't have 1000 hours of multi PIC time. I realize that other major airlines have lower requirements, but it eliminates one airline that could be a really good career.
Those of you that say you want to make PS a career, get back to this thread after you've done a summer in the northeast. 6-8 short legs a day in the middle of summer is highly fatiguing, now do it for 8 days straight.